Domain: tiger-web1.srvr.media3.us Chemistry question of the day | Page 2 | O-T Lounge
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re: Chemistry question of the day

Posted on 10/30/23 at 2:35 pm to
Posted by Oilfieldbiology
Member since Nov 2016
41902 posts
Posted on 10/30/23 at 2:35 pm to
quote:

How to superheat it to that temperature is a trade secret


Is it really?
Posted by Oilfieldbiology
Member since Nov 2016
41902 posts
Posted on 10/30/23 at 2:36 pm to
quote:

Just to be clear, you're using a cartoon as a reference? Also, RAMPAGE!


M for Mancy
Posted by mdomingue
Lafayette, LA
Member since Nov 2010
44609 posts
Posted on 10/30/23 at 2:39 pm to
quote:

There's videos on the interwebs of people burning paper with supe heated steam.



That steam would have to reach 424–475 °F. Which is possible but not sure how common that is. Some applications use very high-temperature steam but most I have seen are in pressurized containers where the boiling point is much higher than 212 F.
Posted by fightin tigers
Downtown Prairieville
Member since Mar 2008
77483 posts
Posted on 10/30/23 at 4:08 pm to
quote:

Just to be clear, you're using a cartoon as a reference?



Well, it piqued my curiosity so I went and researched it.
Posted by fightin tigers
Downtown Prairieville
Member since Mar 2008
77483 posts
Posted on 10/30/23 at 4:13 pm to
quote:

That steam would have to reach 424–475 °F. Which is possible but not sure how common that is.


I would imagine a lot of the industrial plants in the area have steam that temp. Anything over 300# should be sufficient.
Posted by mdomingue
Lafayette, LA
Member since Nov 2010
44609 posts
Posted on 10/30/23 at 6:05 pm to
quote:

I would imagine a lot of the industrial plants in the area have steam that temp. Anything over 300# should be sufficient.



Most of the places that I've worked with steam did not, but very large steam turbines should have steam that is well above that temperature range. Which is why I'm not sure. I think there may be more than a few chemical plants that use high-temperature steam as part of a process as well.
Posted by HighlyFavoredTiger
La
Member since Jun 2018
943 posts
Posted on 10/30/23 at 6:41 pm to
I can tell you for a fact that 1005 degree steam at 2450 pounds of pressure will ignite paper and the straws on a broom and a dry cotton rag, seen it happen to those 3 materials while using them to search for a leak on a main steam line to a 650 MW turbine.
This post was edited on 10/31/23 at 7:46 am
Posted by GetmorewithLes
UK Basketball Fan
Member since Jan 2011
22584 posts
Posted on 10/30/23 at 6:43 pm to
quote:

can superheated steam ignite a flammable substance?


Absolutely. When working with 900 psi steam it is too hot to see a leak so people use straw brooms to wave around a potential leak and yes they will catch on fire.

If you recall Ray Bradbury's novel "Farenheit 451." 451 is the temp that paper allegedly combusts. So if your steam is hotter than 451 F you good.
Posted by Epicenter1
Member since Jul 2023
23 posts
Posted on 10/30/23 at 7:07 pm to
Yes and no. The answers provided by posters with personal experiences of such make me think something else is occurring. Let me explain.

We mix superheated steam and flammable substances everyday in chemical plants like ethylene crackers and reforming units. They are directly mixed in pipes in a very hot environment but react in such a way that is 100% different from burning. In fact these reactions are usually endothermic meaning they require additional heat to keep the reaction going on the outside of the pipes (usually in a furnace).

The answers where people describe brooms catching fire make me think the steam is so hot that the air around it is heated by convection to a temperature higher than the broom bristles flash point. The bristles do NOT combust with steam, only oxygen can do so. Meaning the steam did not displace the oxygen in the vicinity where the broom caught on fire.

Posted by Penrod
Member since Jan 2011
53934 posts
Posted on 10/30/23 at 7:13 pm to
quote:

no...steam is used to extinguish flames by displacing oxygen

Not every substance requires oxygen to burn.
Posted by yakster
Member since Mar 2021
3835 posts
Posted on 10/30/23 at 7:22 pm to
He is correct with his statement. Plants use it specifically for this to superheat a product ie: kerosene to bring it to its flash point to ignite easily. It’s a cost savings method
Posted by MeridianDog
Home on the range
Member since Nov 2010
14539 posts
Posted on 10/30/23 at 7:33 pm to
1000 psi would yield a temp of 546 F. Gasoline will ignite at 536 F.

I am going to say No, since steam at that pressure when released into atmosphere would almost pressure explode, pushing away all oxygen. I do know steam is used to fight fires.
This post was edited on 10/30/23 at 7:38 pm
Posted by Trevaylin
south texas
Member since Feb 2019
10387 posts
Posted on 10/30/23 at 8:14 pm to
check the definition of flammable per wikipedia. Almost all discussion involves oxygen in the process. Yes there are compounds that will auto combust with the oxidizer being part of the molecule. Acetayl Monoperacetate is an example. Solid rocket fuel is another but those are outside the common definition of flammable
Posted by DVinBR
Member since Jan 2013
15480 posts
Posted on 10/30/23 at 8:26 pm to
quote:

superheated steam


at extremely high pressures, terrifying
Posted by lostinbr
Baton Rouge, LA
Member since Oct 2017
12729 posts
Posted on 10/30/23 at 9:26 pm to
quote:

The answers where people describe brooms catching fire make me think the steam is so hot that the air around it is heated by convection to a temperature higher than the broom bristles flash point. The bristles do NOT combust with steam, only oxygen can do so. Meaning the steam did not displace the oxygen in the vicinity where the broom caught on fire.

I mean.. yeah. But I think that still pretty clearly qualifies as being set on fire by the steam.

Steam can very clearly reach temperatures required for autoignition of other materials, you just need an environment where it’s possible for the flammable material to be exposed to that temperature in the presence of oxygen.
Posted by Yewkindewit
Near Birmingham, Alabama
Member since Apr 2012
21751 posts
Posted on 10/30/23 at 10:20 pm to
Both
Posted by LemmyLives
Texas
Member since Mar 2019
14563 posts
Posted on 10/30/23 at 10:24 pm to
quote:

Anyone who has been through demolition school in the Army can answer this ... and the answer is yes.


Bro, the Navy baws (including my parents) are far more obsessive. I was in elementary school when I was taught that if there was a steam leak, don't move. You'll probably live if you don't run around and get yourself cut in half. Just stay still.
Posted by SquatchDawg
Cohutta Wilderness
Member since Sep 2012
19696 posts
Posted on 10/30/23 at 10:29 pm to
quote:

When working with 900 psi steam it is too hot to see a leak so people use straw brooms to wave around a potential leak and yes they will catch on fire


Gotta love redneck ingenuity. Have a life threatening leak with superheated steam under pressure? Need some thermal imaging or high tech to spot it?

frick no…give me a broom.
Posted by CrazyTigerFan
Member since Nov 2003
3577 posts
Posted on 10/30/23 at 10:37 pm to
Is this a chemistry question or a physics question, though? That's the question.
Posted by Rockbrc
Attic
Member since Nov 2015
9577 posts
Posted on 10/30/23 at 11:03 pm to
Yes
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